Tag Archives: chemistry

Is the Red Rectangle a cosmic Rosetta Stone?

THE RED RECTANGLE IS A PECULIAR NEBULA WITH SOME STRANGE CHEMICAL PROPERTIES. CREDIT: NASA/ESA/ HANS VAN WINCKEL (CATHOLIC UNIVERSITY OF LEUVEN) /MARTIN COHEN (UCB).
THE RED RECTANGLE IS A PECULIAR NEBULA WITH SOME STRANGE CHEMICAL PROPERTIES. CREDIT: NASA/ESA/ HANS VAN WINCKEL (CATHOLIC UNIVERSITY OF LEUVEN) /MARTIN COHEN (UCB).

Cracking the puzzle of unusual molecules in deep space that absorb some wavelengths of starlight is like unlocking the secrets of the Rosetta Stone, according to Rob Sharp of the Australian National University’s Research School of Astronomy and Astrophysics. “It’s the longest-standing problem in astronomical spectroscopy,” he says.

The identity of the molecules has been a mystery for 80 years, but Rob has now joined forces with chemists at the University of Sydney to try to crack the molecular code. Continue reading Is the Red Rectangle a cosmic Rosetta Stone?

Dirt solves murder mysteries

Australian detectives can now use a pinch of dirt or a speck of dust to help solve crimes, thanks to techniques developed at the Australian synchrotron.

PHOTO: A SPECK OF DUST OR A PINCH OF DIRT IS NOW ENOUGH TO SOLVE A MURDER. CREDIT: MITARAT
Soil composition is as unique as a fingerprint so scientists can analyse dirt samples and, in theory, match their results to specific regions of the Earth’s surface. Until recently, large sample sizes were needed to make this work.
Continue reading Dirt solves murder mysteries

Spot the nutrients

Tri-colour map of: Fe (red), Cu (green) and Zn (blue) in a grain of barley.
Tri-colour map of: Fe (red), Cu (green) and Zn (blue) in a grain of barley.

South Australian researchers are using the Australian Synchrotron in their work on how to increase levels of iron and other micronutrients in staple grains such as rice and barley. The intense X-rays of the synchrotron can pinpoint where in the grain those micronutrients are found.

One third of the world’s population suffers from iron deficiency. One of the reasons for this is that more than three-quarters of the iron in rice is lost when the outer layers of the grain are removed during milling.

Enzo Lombi and Erica Donner from the Centre for Environmental Risk Assessment and Remediation at the University of South Australia are using the x-ray fluorescence microscopy (XFM) beam to probe grains of rice, barley and other staple grains that have been designed to boost levels of key micronutrients like iron.

The researchers use the intense synchrotron light to produce images showing concentrations of elements, like iron, copper, zinc and selenium.

One of the new plants they are studying is a strain of rice that has multiple copies of the gene for nicotianamine, which is involved in the long-distance transport of iron. The idea is that more iron will be moved into the inner layers of the rice grain.

The technique used by Enzo and Erica is the only one sensitive enough to determine the chemical form of these elements at the low levels found in cereal grains. It will show how much of the iron will be available when it reaches the consumer.

Photo: Tri-colour map of: Fe (red), Cu (green) and Zn (blue) in a grain of barley.
Credit: Enzo Lombi

Centre for Environmental Risk Assessment and Remediation, Enzo Lombi, Tel: +61 8 830 26267, Enzo.Lombi@unisa.edu.au

Yeast to make jet fuels

Yeast to make jet fuels
Dr Claudia Vickers is leading a team looking at modifying baker’s yeast to make aviation fuel. Credit: AIBN.

Baker’s yeast could soon be turning sugar cane into jet fuel. Dr Claudia Vickers from the Australian Institute for Bioengineering and Nanotechnology (AIBN) at the University of Queensland leads a team studying strains which already produce ethanol, industrial chemicals and pharmaceuticals.

The researchers want to use the yeast strains S. cerevisiae to make isoprenoids, chemicals traditionally used to make pharmaceuticals and food additives, but which can also serve as fuel.

The idea is to give the yeast new functions, so they can consume sucrose from cane sugar and produce isoprenoid products, which can be used to replace or supplement traditional jet fuel, without modifying existing aircraft engines or infrastructure.

Claudia’s lab was originally looking at the gut bacteria E. coli, which could also be used to produce isoprenoids, but the yeast is now looking more promising.

Other research groups at The University of Queensland and James Cook University are looking to develop aviation fuel from algae and the oilseed tree Pongamia, both of which can be grown without competing with traditional food crops for land or water.

The University’s sustainable aviation fuel initiative has attracted several backers including Boeing, Virgin Australia, Mackay Sugar, Brisbane-based IOR Energy, and the US-based green energy company Amyris. It is funded by the Queensland State Government.

Photo: Dr Claudia Vickers is leading a team looking at modifying baker’s yeast to make aviation fuel.
Credit: AIBN

Australian Institute for Bioengineering & Nanotechnology, UQ, Claudia Vickers, Tel: +61 7 334 63158, c.vickers@uq.edu.au, www.aibn.uq.edu.au

Silicon solves helicopter corrosion

An inexpensive, environmentally friendly alternative to a toxic coating currently used in Australian naval helicopters has been developed at Monash University in collaboration with CAST Cooperative Research Centre in Melbourne.

A non-toxic coating will reduce environmental and maintenance costs in Seahawk helicopters. Credit: US Navy
A non-toxic coating will reduce environmental and maintenance costs in Seahawk helicopters. Credit: US Navy

The magnesium alloy used to house the gearbox of Royal Australian Navy SeaHawk helicopters is prone to severe corrosion in marine environments, costing millions of dollars in maintenance every year. To protect the alloy from corrosion, it is covered with a chrome-based coating that is toxic to humans and the environment.

Continue reading Silicon solves helicopter corrosion

Fresh Science 2010

Each year we identify early-career scientists with a discovery and bring them to Melbourne for a communication boot camp. Here are some of their stories.

More at www.freshscience.org.au

Print your own lasers, lights and TV screens

Print your own lasers, lights and TV screens
Jacek Jasieniak sprinkling quantum dots. Credit: Jacek Jasieniak

Imagine printing your own room lighting, lasers, or solar cells from inks you buy at the local newsagent. Jacek Jasieniak and colleagues at CSIRO, the University of Melbourne and the University of Padua in Italy, have developed liquid inks based on quantum dots that can be used to print such devices and in the first demonstration of their technology have produced tiny lasers. Quantum dots are made of semiconductor material grown as nanometre-sized crystals, around a millionth of a millimetre in diameter. The laser colour they produce can be selectively tuned by varying their size.

Cling wrap captures CO2
Colin Scholes operates a test rig for his carbon capture membrane. Credit: CO2 CRC

Cling wrap captures CO2

High tech cling wraps that ‘sieve out’ carbon dioxide from waste gases can help save the world, says Melbourne University chemical engineer, Colin Scholes who developed the technology. The membranes can be fitted to existing chimneys where they capture CO2 for removal and storage. Not only are the new membranes efficient, they are also relatively cheap to produce. They are already being tested on brown coal power stations in Victoria’s La Trobe Valley, Colin says. “We are hoping these membranes will cut emissions from power stations by up to 90 per cent.”

Continue reading Fresh Science 2010

Cementing a greener future

Making cement is the third largest source of carbon emissions in the world after the burning of fossil fuels and deforestation—but the Australian roads of the future could be paved with cement that is made in a process that generates less than half the carbon emissions of traditional methods.

Green cement is now becoming part of Victoria’s roads. Credit: Australian Synchrotron.
Green cement is now becoming part of Victoria’s roads. Credit: Australian Synchrotron.

Each year, the world produces about 12 billion tonnes of concrete and about 1.6 billion tonnes of its key ingredient, Portland cement, which is generated by breaking calcium carbonate into carbon dioxide and calcium oxide.

This produces some 2 billion tons of carbon dioxide—so the Geopolymer and Mineral Processing Group (GMPG) at the University of Melbourne, now led by Dr John Provis, went looking for a lower carbon way of making cement.

They have now developed binders and concretes based on a low-CO2 aluminosilicate compounds called geopolymers.

Continue reading Cementing a greener future

Algae that make biofuels and hydrogen

IMB_Ben_with_algae An Australian researcher is leading an international team of scientists developing a clean source of energy from microalgae. The team have developed one algae that not only makes oil for biodiesel production but also generates hydrogen. Commercial hydrogen production uses fossil fuels and produces carbon dioxide.

Continue reading Algae that make biofuels and hydrogen